Introduction to Solid State Chemistry 3.091SC MIT
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Details
Basic principles of chemistry and their application to engineering systems. The relationship between electronic structure, chemical bonding, and atomic order. Characterization of atomic arrangements in crystalline and amorphous solids: metals, ceramics,
semiconductors, and polymers (including proteins). Topical coverage of organic chemistry, solution chemistry, acid-base equilibria, electrochemistry, biochemistry, chemical kinetics, diffusion, and phase diagrams. Examples from industrial practice (including
the environmental impact of chemical processes), from energy generation and storage (e.g. batteries and fuel cells), and from emerging technologies (e.g. photonic and biomedical devices).
Language: English
Professors: Michael Williams
Units: 62
Lesson content
- Course Introduction
- Lec 1 Introduction
- Lec 2 Classification Schemes for the ElementsMendeleyev and the Periodic Table
- Lec 3 Rutherford Model of the Atom, Bohr Model of Hydrogen
- Lec 4 Atomic Spectra of Hydrogen, Matter/Energy Interactions Involving Atomic Hydrogen
- Lec 5 The Shell Model (Bohr-Sommerfeld Model) and Multi-electron Atoms
- Lec 6 De Broglie, Heisenberg, and Schrödinger
- Lec 7 Octet Stability by Electron Transfer: Ionic Bonding
- Lec 8 Born-Haber Cycle
- Lec 9 Electronegativity, Partial Charge, Polar Bonds and Polar Molecules
- Lec 10 LCAO MO, Energy Level Diagrams for H2, He2, Li2
- Lec 11 The Shapes of Molecules, Electron Domain Theory, Secondary Bonding
- Lec 12 Metallic Bonding, Band Theory of Solids (Heitler and London), Band Gaps in Metals, Semiconductors, and Insulators, Absorption Edge of a Semiconductor
- Lec 13 Intrinsic and Extrinsic Semiconductors, Doping, Compound Semiconductors, Molten Semiconductors
- Lec 14 Introduction to the Solid State, the 7 Crystal Systems, the 14 Bravais Lattices
- Lec 15 Properties of Cubic Crystals: Simple Cubic, Face-centered Cubic, Body-centered Cubic, Diamond Cubic
- Lec 16 Characterization of Atomic Structure: The Generation of X-rays and Moseley's Law
- Lec 17 X-ray Spectra, Bragg's Law
- Lec 18 X-ray Diffraction of Crystals: Diffractometry, Debye-Scherrer, Laue Crystal Symmetry
- Lec 19 Defects in Crystals: Point Defects, Line Defects, Interfacial Defects, Voids
- Lec 20 Amorphous Solids, Glass Formation, Inorganic Glasses: Silicates
- Lec 21 Engineered Glasses: Network Formers, Network Modifiers, Intermediates Properties of Silicate Glasses
- Lec 22 Chemical Kinetics: The Rate Equation, Order of Reaction, Rate Laws for Zeroth, First, and Second Order Reactions Temperature Dependence of Rate of Reaction
- Lec 23 Diffusion: Fick's First Law and Steady-state Diffusion, Dependence of the Diffusion Coefficient on Temperature and on Atomic Arrangement
- Lec 24 Fick's Second Law (FSL) and Transient-state Diffusion; Error Function Solutions to FSL
- Lec 25 Solutions: Solute, Solvent, Solution, Solubility Rules, Solubility Product
- Lec 26 Acids and Bases: Arrhenius, Brønsted-Lowry, and Lewis Definitions, Acid Strength and pH
- Lec 27 Organic Chemistry: Basic Concepts, Alkanes, Alkenes, Alkynes, Aromatics, Functional Groups, Alcohols and Ethers, Aldehydes and Ketones, Esters, Amines
- Lec 28 Organic Glasses - Polymers: Synthesis by Addition Polymerization and by Condensation Polymerization
- Lec 29 Structure-property Relationships in Polymers, Crystalline Polymers
- Lec 30 Biochemistry: The Amino Acids, Peptides, and Proteins
- Lec 31 Biochemistry: Protein Structure
- Lec 32 Biochemistry: Lipids, Nucleic Acids & DNA
- Lec 33 Unary Phase Diagrams
- Lec 34 Binary Phase Diagrams: Complete Solubility
- Lec 35 Binary Phase Diagrams: Limited Solubility
- Exam 1, Problem 1
- Exam 1, Problem 2
- Exam 1, Problem 3
- Exam 1, Problem 4
- Exam 1, Problem 5
- Exam 1, Problem 6
- Exam 2, Problem 1
- Exam 2, Problem 2
- Exam 2, Problem 3
- Exam 2, Problem 4
- Exam 2, Problem 5 (Part A)
- Exam 2, Problem 5 (Part B)
- Exam 2, Problem 5 (Part B)
- Exam 3, Problem 1
- Exam 3, Problem 2
- Exam 3, Problem 3
- Exam 3, Problem 4
- Exam 3, Problem 5
- Final Exam A, Problem 8
- Final Exam A, Problem 9
- Final Exam A, Problem 10
- Final Exam B, Problem 5
- Final Exam B, Problem 6
- Final Exam B, Problem 7
- Final Exam B, Problem 11
- Final Exam B, Problem 13
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