Freshman Organic Chemistry (CHEM 125B) Yale
Online Free Online Course by
World Mentoring Academy
Online
/ Free Online Course
Details
Continuation of Freshman Organic Chemistry I (CHEM 125a), the introductory course on current theories of structure and mechanism in organic chemistry for students with excellent preparation in chemistry and physics. This semester treats simple and complex
reaction mechanisms, spectroscopy, organic synthesis, and some molecules of nature.
Resources: OpenCourseware from Yale, UC Berkeley, Stanford, Husson along with many of the World's finest University's.
Language: English
Professors: Joshua Coleman, Michael Williams
Units: 38
Lesson content
- Lec 1. Mechanism: How Energies and Kinetic Order I...
- Lec 2. Peculiar Rate Laws, Bond Dissociation Energies, and Relative Reactivities
- Lec 3. Rate and Selectivity in Radical-Chain Reactions
- Lec 4. Electronegativity, Bond Strength, Electrostatics, and Non-Bonded Interactions
- Lec 5. Solvation, H-Bonding, and Ionophores
- Lec 6. Brønsted Acidity and the Generality of Nucleophilic Substitution
- Lec 7. Nucleophilic Substitution Tools - Stereochemistry, Rate Law, Substrate, Nucleophile
- Lec 8. Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent Carbon
- Lec 9. Pentavalent Carbon? E2, SN1, E1
- Lec 10. Cation Intermediates. Alkenes: Formation, Addition, and Stability
- Lec 11. Carbocations and the Mechanism of Electrophilic Addition to Alkenes and Alkynes
- Lec 12. Nucleophilic Participation During Electrophilic Addition to Alkenes
- Lec 13. Addition to Form Three-Membered Rings: Carbenoids and Epoxidation
- Lec 14. Epoxide Opening, Dipolar Cycloaddition, and Ozonolysis
- Lec 15. Metals and Catalysis in Alkene Oxidation, Hydrogenation, Metathesis, and Polymerization
- Lec 16. Isoprenoids, Rubber, and Tuning Polymer Properties
- Lec 17. Alkynes. Conjugation in Allylic Intermediates and Dienes
- Lec 18. Linear and Cyclic Conjugation Theory. 4n+2 Aromaticity
- Lec 19. Aromatic Transition States: Cycloaddition and Electrocyclic Reactions
- Lec 20. Electronic and Vibrational Spectroscopy
- Lec 21. Functional Groups and Fingerprints in IR Spectroscopy. Precession of Magnetic Nuclei
- Lec 22. Medical MRI and Chemical NMR
- Lec 23. Diamagnetic Anisotropy and Spin-Spin Splitting
- Lec 24. Higher-Order Effects, Dynamics, and the NMR Time Scale
- Lec 25. C-13 and 2D NMR. Electrophilic Aromatic Substitution
- Lec 26. Aromatic Substitution in Synthesis: Friedel-Crafts and Moses Gomberg
- Lec 27. Triphenylmethyl and an Introduction to Carbonyl Chemistry
- Lec 28. Mechanism and Equilibrium of Carbonyl Reactions
- Lec 29. Imines and Enamines. Oxidation and Reduction
- Lec 30. Oxidation States and Mechanisms
- Lec 31. Periodate Cleavage, Retrosynthesis, and Green Chemistry
- Lec 32. Measuring Bond Energies: Guest Lecture by Prof. G. Barney Ellison
- Lec 33. Green Chemistry. Acids and Acid Derivatives
- Lec 34. Acids and Acid Derivatives
- Lec 35. Acyl Insertions and [gr]α-Reactivity
- Lec 36. [gr]α-Reactivity and Condensation Reactions
- Lec 37. Proving the Configuration of Glucose and Synthesizing Two Unnatural Products
- Lec 38. Review: Synthesis of Cortisone
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